Dr. Miquel Navarro. Institute for Chemical Research (IIQ)
Viernes, 13 de marzo de 2020. 12:30 h
Salón de Grados de cicCartuja
Metal-ligand bond interactions serve both to modulate the electronic properties of the metal center and to influence the steric environment of the metal coordination sphere, thus providing excellent control over the structure and reactivity of the coordinated metal center. Therefore, the design and development of new ligand motifs is crucial to advance the area of organometallic chemistry and homogeneous catalysis.1
Herein, the design and development of different class of ligands, from P-Stereogenic Phosphines2 and hemilabile/chelating P^N ligands3, to more electronically flexible ligands such as Mesoionic N-Heterocyclic Carbenes (NHCs)4 and Pyridylideneamide (PYA)5, will be discussed. In addition, special attention will be given to their use in organometallic transformation and homogenous catalysis.
References
[1] Lundgren R. J. and Stradiotto M., Ligand Design in Metal Chemistry: Reactivity and Catalysis, John Wiley & Sons, Chichester, UK, 2016.
[2] Navarro, M., Vidal, D., Clavero, P., Grabulosa, A. and Muller G. Organometallics 2015, 34, 973–994.
[3] a) Navarro, M., Toledo, A., Joost, M., Amgoune, A., Mallet-Ladeira, S. and Bourissou, D. Chem. Commun., 2019, 55, 7974–7977; b) Navarro, M., Toledo, A., Mallet-Ladeira, S., Sosa-Carrizo. E. D., Miqueu, K and Bourissou, D. Chem. Sci., 2020, DOI:10.1039/c9sc06398f.
[4] Navarro, M., Wang, S., Müller-Bunz, H., Redmond, G., Farràs, P. and Albrecht. M. Organometallics 2017, 36, 1469–1478.
[5] a) Navarro, M., Li, M., Müller-Bunz, H., Bernhard, S. and Albrecht, M. Chem. Eur. J. 2016, 22, 6740– 6745; b) Navarro, M., Smith, C. A. and Albrecht, M. Inorg. Chem. 2017,56, 11688–11701; c) Navarro, M., Rosar, V., Montini, T., Milani, B. and Albrecht, M. Organometallics 2018, 37, 3619–3630.
Estudiantes de toda Europa explorarán cómo la innovación comparte procesos comunes en el arte y en la ciencia.
Dos investigadores del cicCartuja galardonados: Isabel Cruz-Gallardo, IBVF, y Juan C. Muñoz-García, IIQ.
Por primera vez se desarrolla un método sencillo y de bajo coste que une el compuesto metálico con esta especia
La Sociedad Española de Catálisis reconoce como mejor del 2014 a su trabajo doctoral realizado en el ICMS
El cicCartuja colabora en su organización para estrechar lazos entre el sector privado y los organismos públicos de investigación
The Academy acknowledges his studies of functional nanomaterials with applications in photonics, electronics and sensors